Dear Friends,
Mr Louis provided a nice answer to the problem. Further clarifications to this problem are as follows:-
· The ferrite in question for austenitic stainless steel is delta ferrite, not alpha-ferrite (the main metallurgical phase in all ferritic steels)
· Delta Ferrite, to the extent of 3-8.FN (depending on the grade of austenitic S.S e.g 304/316/321/347…. ) is required in the weld metal, to prevent hot cracking. This is allowed by any boiler and pressure vessel code, such as ASME, API etc.
· Delta Ferrite is a high temperature phase. It typically precipitates and solidifies along the grain boundary of austenite grains in the weld metal. Welds being a cast structure would definitely have some delta ferrite in 300 series of alloys (e.g. 304,316,321, 347 …. etc). Delta Ferrite in the above amount is mandatory for austenitic S.S weld metal
· The amount of ferrite in the weld could be measured due to residual ferromagnetism in the weld. This occurs due to presence of ferrite, which is magnetic. Usually Ferrite is measured by Ferrite Scope.
Base metal or weld fillers would not have residual magnetism, because they do not contain delta ferrite in the processed and finished structure. Ferrite may be formed during original casting of plates, however through subsequent thermal processing (hot rolling… etc) it almost gets converted to austenite.
Note this residual magnetism does not have any or significant effect to the intended services of austenitic stainless steels.
Thanks.
Pradip Goswami, P.Eng. IWE.
Senior Engineer/Specialist(Welding-Metallurgy)
Engineering & Training Services Division
ONTARIO POWER GENERATION Inc.
PO Box-2000, RR-55(South)
Nanticoke, Ontario,N0A1L0
Tel:-(519) 587-2201, Ext 3107--in Nanticoke
(416) 231-4111, Ext 5925--in Kipling,Toronto
Fax: (519) 587-6814
-----Original Message-----
From: pgoswami [mailto:pgoswami@quickclic.net]
Sent: Friday, March 19, 2010 6:23 AM
To: GOSWAMI Pradip -THERMAL
Subject: FW: Re: [MW:4087] Magnetism in SS 304 & 321 after welding
Pradip Goswami
88,Garth Trails Crescent
Hamilton,Ontario, L9B2X1,Canada
Tel-905-679-9677
From: materials-welding@googlegroups.com [mailto:materials-welding@googlegroups.com] On Behalf Of A D
Sent: Tuesday, January 19, 2010 5:19 AM
To: materials-welding@googlegroups.com
Subject: [Norton AntiSpam] Re: [MW:4087] Magnetism in SS 304 & 321 after welding
Hi Sunnel, In Austenitic stainless steel welding one of the susceptibility problems is hot cracking. So avoid this problem, need some delta ferrite in welding ( which is magnetism) .So consumable manufacturing is carried out based on this ferrite requirement. In my previous projects 3 to 8 FN requirement is given by client specification, For clear detail please refer AWS handbook - Volume 1. Louis Welding Engineer Singapore
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