- Reheat, or stress-relief, cracking is unusual in standard grades of austenitic stainless steels· but may occur in alloys that form MC-type carbides during the stress-relief thermal cycle. Type 347, which contains Nb and forms NbC, is known to be susceptible to this form of cracking . Higher-carbon heat-resisting alloys such as 304 Hand 316H may also be susceptible to reheat cracking, During welding, alloy carbides dissolve in the high-temperature HAZ adjacent to the fusion boundary. The weld metal also contains carbon and carbide-forming alloy elements in solution. When the weldment is reheated during a post weld;stress relief, carbides precipitate in the grain interiors and strengthen these regions relative to the grain boundaries. If significant stress relaxation occurs in this same temperature range, failure can occur preferentially along the grain boundaries. This phenomenon has been observed in both the HAZ and weld metal. The combination of stress relaxation and NbC precipitation in the grain interiors promoted cracking in this weld metal.
NACE RP-170-2004 recommends stabilization Anneal @ 843-900 deg C for a period of 2-4 hrs for re-formation of Nb-Carbides in 347H S.S and avoid formation of Cr-Carbides (which will destroy the basic corrosion resistance of 347 H S.S). See the attached Q&A from Damian Kotecki as illustration. However selection of the right PWHT cycle is left up to the fabricator.
In you case a combination of one or more of the recommendations below may help to solve the problem:-
- Check the Max, Nb+Ta in the base metal and welding consumable.For base metal the limit is 10x %C and not more than 1.00%. for weld 8 x %C and not more than 1.00%.For weld metals the first choice, 8 x %C would be preferred.
- What's the ferrite level in welding consumables, typical requirement for SS 347 is 5FN, Minm, 8 FN max. Higher ferrite may cause sigma phase during service exposure between 425-800 deg C. For the present case i.e stabilizing anneal at 900 deg C if the initial ferrite in the weld is greater than the specified range above , there would be chances of sigma phase, which would embrittle the weld and reduce ductility.
- Change the stabilizing cycle.Instead of soaking for 3 hrs @870 deg C.follow a reduced duration PWHT cycle, e.g 870deg C, 1hr typically -for this thickness. Note the minimum thickness is 6mm which is the governing thickness for PWHT soaking time.
You may find the article from Dr Damian Kotecki, as quite informative on this issue.
Thanks.
From: materials-welding@googlegroups.com [mailto:materials-welding@googlegroups.com] On Behalf Of praveen alavandar
Sent: Saturday, January 08, 2011 12:34 AM
To: materials-welding@googlegroups.com
Subject: Re: [MW:9147] MW:9116-PWHT Of 347H
Dear Mr.Bazrafshan, There may be two reasons why your weld would have cracked. First it can be weld solidification cracking. what is the orientation of the crack? is it a longitudinal centerline crack, running along the weld or is it transverse? If you find a longitudinal crack running along the weld centre line, then it shoudl be weld solification crackng, Please find attached suutala diagram for predicting weld solidification cracking from weld metal composition, you need to calculate the Cr and Ni equivalents and also P + S content of the weld metal. You also need to check the ferrite content of the weld metal using magnegage or ferrite scope adjacent to the crack, you'll need a flat surface for you probe to sit on it. If cracking is visible on the joint, I think that shoudl be on your SMAW weld.Too low ferrite can do the damage. You stabilizing heat treatment would have opened up the crack making it more visible. Try LPT on one of the as welded joints before heat treatment for screening any cracks. I will recommed you to make a weld pad for both your GTAW and SMAW welding consumables and do the chemical analysis of the undiluted weld metal. You can also check the WRC 1988 or 1992 diagram to understand expected ferrite content and the solidfication mode of your weld metal, if you solification is fully austentic or austenite + ferrite (AF) mode then chances of a solification cracking is very high. if it is FA mode then it cna be ruled out. Second reason may be you would not have maintained cleanliness of the joint and consumables because oil / grease can introduce P & S into your weld metal and give rise to solidification craking. Try depositing a convex weld, which is better than a concave weld in these kind of situations. Hope this helps. Regards, A.Praveen Senior Welding Engineer Muscat --- On Fri, 1/7/11, pgoswami <pgoswami@quickclic.net> wrote:
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